Jim what your seeing is nothing uncommon with a chamber that has a 45 degree end.
I can find a ring paper or lead depending if I use a PP or GG bullet.
That is the biggest cause of lead in the bore. It starts at the chamber end and shot after shot it gets smeared forward.
This will even happen using a PP bullet with very thin paper.
If you have a good bore scope you can see that ring after shooting in a clean barrel if the gases didn't blow it out.
If your case is short and a lube groove ahead of the case mouth will stop a lot of that lead ring problem, but a PP bullet you will get the ring. It will be there if you look for it.
Below are some rings I found from 7 out of 10 shots fired with brass .006" short of the chamber end. The tighter the case fits the smaller in thickness the rings will be.
Kurt